松辽盆地东北缘姚家组岩石地球化学特征、物源构造环境及其与铀成矿关系浅析
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本文为中国核工业地质局“松辽盆地北部砂岩型铀矿资源调查评价”项目(编号201709)和国防科工局核能开发项目“松辽盆地砂岩型铀矿综合预测评价技术研究”项目(编号20171403)联合资助的成果。


Geochemical characteristics, provenance, tectonic settings and their relationships with uranium mineralization of the rocks of the Yaojia Formation in the northeastern margin of the Songliao basin
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    摘要:

    对于砂岩型铀矿找矿工作及评价而言,赋铀砂体的物源是其关键。松辽盆地东北缘姚家组是其重要的赋矿层位,本文通过对松辽盆地东北缘姚家组砂岩及蚀源区花岗岩21件样品进行主量、微量、稀土元素及磷灰石裂变径迹年代学进行分析,并结合前人成果,旨在探讨姚家组氧化-还原条件、源区构造背景及古气候演变对铀成矿的影响。研究表明:① 姚家组砂岩主要为长石岩屑砂岩,与蚀源区花岗岩具有相似的地球化学特征,均具有高硅(SiO2=66. 38%~77. 71%)、富碱(Na2O+K2O=6. 22%~9. 35%)、铝(Al2O3=12. 11%~17. 25%)、贫镁钙(MgO=0. 13%~1. 15%,CaO=0. 21%~2. 41%)的特征,稀土总量不高(∑REE=84. 29×10-6~239. 38×10-6),轻稀土分馏系数(La/Sm)N为2. 62~4. 69,重稀土分馏系数(Gd/Yb)N为1. 48~3. 30,具有壳源岩浆特点。② 元素B、Sr/Ba、B/Ga组合及U/Th、V/(V+Ni)、V/Cr、Ni/Co的组合指示姚家组沉积时的古水体介质均为富氧的淡水环境,Fe2+/Fe3+指示姚家组成岩阶段经历了后生还原作用。③ ICV值为0. 65~0. 74,平均值为0. 69,均小于1,修正后的CIA平均值为64. 01,代表可能经历了再旋回作用或者首次沉积过程中经历了中等风化作用。④ 姚家组砂岩在La/Th-Hf和Co/Th-La/Th判别图解上显示沉积物源主要来自上地壳的长英质岩石,且在构造判别图解上,姚家组砂岩和蚀源区花岗岩样品几乎全部落入活动大陆边缘与火山弧花岗岩区,显示其构造背景为活动大陆边缘环境。⑤ 磷灰石裂变径迹年代学表明松辽盆地北部在中晚侏罗世以来整体为持续降温过程,可分为4个阶段:即晚侏罗世—晚白垩世初(160~90 Ma)的急剧冷却隆升过程;晚白垩世初—古近纪中新世(90~40 Ma)缓慢冷却(稳定)阶段;古近纪中新世—古近纪末(40~25 Ma)较快速升温阶段;古近纪末(25~0 Ma)缓慢冷却(稳定)阶段,其中在晚白垩世—古近纪期间发生了一次构造岩浆热事件改造的作用,是后期大规模铀成矿物质基础,为铀成矿作用创造了必需的构造和水动力条件,且在区域上基性岩浆活动与主要铀成矿作用同期,表明在松辽盆地北部有可能存在热液或热动力辅助成矿作用。综合以上分析认为,松辽盆地东北缘姚家期的构造条件、古气候、富氧古水体、有利的沉积相及厚大砂体对本区砂岩型大规模成矿具有重要地质意义。

    Abstract:

    Characterising the provenance of uranium-enriched sand bodies is important for the prospecting and evaluation of sandstone-type uranium deposits. The Yaojia Formation is an important ore-forming horizon in the northeastern margin of the Songliao basin. In this paper, the major elements, trace elements, rare-earth elements and AFT tests of the 21 granite samples that were from the 〖JP2〗Yaojia Formation in the eroded provenance area of the northeastern margin of the northern Songliao were analyzed by ICP-MS. This study aimed to explore the impact of oxidation-reduction conditions, provenance, tectonic settings and paleo-climate evolution on uranium mineralization. The results revealed that: ① The sandstone of the Yaojia Formation is dominated by feldspar lithic sandstone. It has similar geochemical characteristics to the granites in eroded provenance area, with high silicon content (SiO2=66. 38%~77. 71%), rich in alkali (Na2O+K2O=6. 22%~9. 35%) and aluminum (Al2O3=12. 11%~17. 25%), but poor in magnesium and calcium (MgO=0. 13%~1. 15%,CaO=0. 21%~2. 41%). It shows the characteristics of crust-derived magma, with low total rare earth amount (∑REE=84. 29×10-6~239. 38×10-6), light rare earth fractionation coefficient (La/Sm)N of 2. 62~4. 69, heavy rare earth fractionation coefficient (Gd/Yb)N of 1. 48~3. 30 with obvious crustal source magma characteristics. ② The combination of element B, Sr/Ba, B/Ga and the combination of U/Th, V/V+Ni, V/Cr, Ni/Co indicated that the paleo-water medium was an oxygen-rich freshwater environment when the Yaojia Formation was deposited. Fe2+/Fe3+ indicated that the rocks of the Yaojia Formation underwent epigenetic reduction. ③ The ICV value ranged from 0. 65 to 0. 74, with an average of 0. 69. The revised average CIA value was 64. 01. It indicated that the rocks of the Yaojia Formation might have undergone recycling or moderate weathering during the first deposition. ④ The La/Th-Hf and Co/Th-La/Th discriminate diagrams showed that the sandstones of the Yaojia Formation were mainly sourced from the felsicprovenance area of the upper crust. The structure discriminate diagrams showed that almost all the sandstones of the Yaojia Formation and the granite samples of eroded provenance area fell in the range of active continental margin and volcanic arc granite, indicating the tectonic setting was an active continental margin environment. ⑤ According to the AFT tests, north of Songliao basin experienced a continuous cooling process from the Middle Jurassic,which can be divided into four stages. From Late Jurassic to Late Cretaceous (160~90 Ma), the whole northern basin underwent rapid cooling and uplift process;from Late Cretaceous to Paleogene Mesozoic (90~40 Ma), the northern basin underwent a slow cooling stage; from Paleogene Middle Epoch to Late Paleogene (40~25 Ma), the northern basin was at a relatively rapid warming stage; since Late Paleogene (25~0 Ma), there was weak tectonism. Therefore, the Songliao basin underwent a magmatic thermal event during the Late Cretaceous to Paleogene, which is the late large-scale uranium metallogenic material base, for uranium mineralization and hydrodynamic conditions to create the necessary structure, and the upper basic magmatic activity in the region was the same as the main uranium mineralization, indicating that may also be hydrothermal or thermodynamic assisted mineralization in the north of the Songliao basin. Based on the above comprehensive analyses, it is concluded that the paleo-climate, oxygen-rich paleo-water body, favorable sedimentary facies and thick sand bodies had important geological significance for the large-scaled mineralization of the sandstone-type uranium in the northeastern margin of the Songliao basin.

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李研,聂逢君,严兆彬.2021.松辽盆地东北缘姚家组岩石地球化学特征、物源构造环境及其与铀成矿关系浅析[J].地质学报,95(11):3472-3491.
Li Yan, Nie Fengjun, Yan Zhaobin.2021. Geochemical characteristics, provenance, tectonic settings and their relationships with uranium mineralization of the rocks of the Yaojia Formation in the northeastern margin of the Songliao basin[J]. Acta Geologica Sinica,95(11):3472-3491.

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  • 收稿日期:2020-04-26
  • 最后修改日期:2021-01-24
  • 在线发布日期: 2021-11-23