东秦岭东段五垛山花岗岩基白草垛花岗伟晶岩微量元素富集型锆石特征及岩浆热液过程
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本文为国家自然科学基金项目(编号 42172236、41872233、41872235)、河南省重点研发与推广专项项目(编号 212102310030)、自然资源部成矿作用与资源评价重点实验室开放基金项目(编号 ZS006)、资源与生态环境地质湖北省重点实验室开放基金项目(编号 KJ2022- 35)、长安大学西部矿产资源与地质工程教育部重点实验室开发基金项目(编号 300102261505)和南阳理工学院交叉科学研究项目联合资助的成果。


Trace element enriched zircon and magmatic hydrothermal process of Baicaoduo granitic pegmatite in Wuduoshan batholith in the eastern part of East Qinling
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    摘要:

    锆石是岩石中常见的副矿物,锆石晶体结构和地球化学特征的变化可以记录热液蚀变过程。东秦岭东段白草垛花岗伟晶岩中识别出三种类型锆石。类型一锆石具有明显的振荡环带,部分锆石边部有少量裂隙,微量元素含量相对较低,重稀土元素(HREE)富集,具明显Ce的正异常和Eu的负异常,指示其为岩浆锆石。类型二锆石具核- 幔- 边结构,边部裂隙发育,核部与类型一锆石具有相似的CL和微量元素特征,为岩浆锆石;幔部呈深色海绵状,内部结构不均匀,偶见环带锆石残留,微量元素含量较高,具有较高的U和Th含量,Ce异常不明显,具热液锆石特征,为热液沿着裂隙进入锆石内部不完全热液改造的结果。类型三锆石的结构特征和微量元素含量与类型二锆石的幔部相似,具有异常高U和Th含量以及较高的Dα值,为类型二锆石近完全热液改造的结果。花岗伟晶岩作为岩浆演化晚期的产物,经过结晶分异,残留的岩浆热液富集微量元素,岩浆热液沿着锆石的裂隙进入晶体内部对锆石经过不同程度热液改造,形成了花岗伟晶岩中不同类型的锆石。

    Abstract:

    Zircon is an accessory mineral in igneous rocks and can provide a record of hydrothermal alteration through variations in crystal structures, and geochemical properties. In samples of altered granitic pegmatite from the Baicaoduo region in the eastern part of East Qinling, three different forms of zircon were found. Type 1 zircons feature pronounced oscillatory zones, low trace element levels, and are concentrated in the heavy rare earth elements (HREE). Some Type 1 zircons also have a modest number of fractures near the rim. They are magmatic zircons because the Ce exhibits clear positive anomalies and significant negative Eu anomalies. Type 2 zircons have developed rim fractures and a core- mantle- rim structure. The core has similar CL and trace element characteristics to Type 1 zircon, which is magmatic zircon. Type 2 zircon mantle has dark spongy, uneven internal structure, occasionally contains zircon residue, a high trace element content, and inconspicuous Ce anomaly. It has hydrothermal zircon characteristics due to incomplete reworking of hydrothermal solution into zircon along the fracture. The Type 3 and Type 2 zircon mantles have comparable structural characteristics and trace element content, with abnormally high U and Th content and high Dα value, which is the result of complete hydrothermal reworking of Type 2 zircon. As a byproduct of later magmatic development known as granitic pegmatite, leftover magmatic hydrothermal enhances trace elements by crystallization differentiation. In granitic pegmatite, the zircon is reworked to varied degrees by the magmatic hydrothermal that penetrates the crystal via the zircon's fracture.

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陈国超,张晓飞,裴先治,李瑞保,李佐臣,魏均启,陈孝珍,季宪军,张勇.2023.东秦岭东段五垛山花岗岩基白草垛花岗伟晶岩微量元素富集型锆石特征及岩浆热液过程[J].地质学报,97(3):688-704.
Chen Guochao, Zhang Xiaofei, Pei Xianzhi, Li Ruibao, Li Zuochen, Wei Junqi, Chen Xiaozhen, Ji Xianjun, Zhang Yong.2023. Trace element enriched zircon and magmatic hydrothermal process of Baicaoduo granitic pegmatite in Wuduoshan batholith in the eastern part of East Qinling[J]. Acta Geologica Sinica,97(3):688-704.

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  • 收稿日期:2022-04-11
  • 最后修改日期:2022-07-04
  • 录用日期:2022-07-05
  • 在线发布日期: 2023-03-30