松辽盆地古龙凹陷热流体活动及其地质意义——来自青山口组页岩中的证据
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本文为国家自然科学基金项目(编号42372155)和中国石油天然气集团公司重大科技攻关项目(编号2023ZZ15YJ01)联合资助的成果


Hydrothermal fluid activity in the Gulong sag, Songliao basin, and its geological significance: Evidence from the shale of the Qingshankou Formation
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    摘要:

    为了解松辽盆地热流体的活动范围和特征,分析热流体活动对储层物性的影响以及其与现今超压的关系,本文通过铸体薄片、扫描电镜、电子探针、黏土矿物XRD、包裹体均一温度、镜质组反射率、岩石热解参数及碳酸盐胶结物的碳、氧同位素等分析测试方法,结合前人研究成果,对松辽盆地古龙凹陷青山口组页岩开展了相关研究。结果表明,在与构造热事件和岩浆活动相关的热流体影响下,储层表现出镜质组反射率与岩石热解参数异常、自生黏土矿物转化速率加快、大量流体包裹体均一温度高于地层最大埋深温度、碳酸盐胶结物的δ18O和自生黄铁矿的δ34S值与岩浆岩同位素区间值重合、热液矿物组合发育等特点。古龙凹陷深部热流体的主要活动范围在2000 m以下。青山口组页岩的高孔、高渗带与热流体活动段和超压发育带吻合。热流体活动伴随大量无机CO2侵入页岩储层中,在一定程度上抑制了碳酸盐胶结作用,促进了易溶矿物的溶解,导致储层中次生孔隙发育,从而改善了页岩储层的物性。此外,热流体活动加速了有机质的热演化,促使烃源岩大量生烃,提高了烃源岩的产烃能力。目前古龙凹陷地层的异常压力主要归因于生烃膨胀作用,热流体活动及其水热增温对维持超压也有一定贡献。

    Abstract:

    To understand the activity range and characteristics of hydrothermal fluids in the Songliao basin and analyze their influence on the porosity- permeability of the shale reservoir,as well as their relationship with present- day overpressure, this study focuses on the Qingshankou Formation shale in the Gulongsag. Our research combines microscopic and scanning electron microscope observations, electron probe measurement, XRD analyses of clay minerals, homogenization temperature and Laser Raman spectroscopy of fluid inclusions, vitrinitereflectance, rock pyrolysis, and carbon and oxygen isotope analysis of carbonate cement. We integrate these findings with previous research results. Our results show that hydrothermal fluids, associated with tectonothermal events and magmatic activity, have significantly impacted the shale reservoir. This is evidenced by anomalies invitrinite reflectance and rock pyrolysis parameters, accelerated transformation rates of authigenic clay minerals, and a higher fluid inclusion homogenization temperature than expected based on maximum buried depth. The δ18O values of carbonate cement and δ34S values of authigenic pyrite are consistent with those of magmatic rocks,further supporting the influence of hydrothermal fluids. We identified a typical hydrothermal mineral assemblage in the shale, suggesting that deep hydrothermal fluid activity primarily occurred below 2000 m. The zones of high porosity and permeability in the Qingshankou shale coincide with zones of hydrothermal fluid activity and overpressure development. The intrusion of hydrothermal fluids, rich in inorganic CO2, inhibited carbonate cementationto some extent and promoted the dissolution of soluble minerals, leading to the formation of secondary pores and improving the physical properties of the shale reservoirs. Meanwhile, hydrothermal activity accelerated the thermal maturation of organic matter,enhancing hydrocarbon generation from the source rocks and increasing its hydrocarbon production capacity. We propose that the abnormal pressure in the Gulong sag is mainly due to hydrocarbon- generating expansion, with hydrothermal activity and its associated heating effect also contributing to the maintenance of overpressure.

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谈泽,罗静兰,赵燕,潘会芳,严敏,高波,罗丹婷,张扬,陈国龙.2025.松辽盆地古龙凹陷热流体活动及其地质意义——来自青山口组页岩中的证据[J].地质学报,99(2):551-567.
TAN Ze, LUO Jinglan, ZHAO Yan, PAN Huifang, YAN Min, GAO Bo, LUO Danting, ZHANG Yang, CHEN Guolong.2025. Hydrothermal fluid activity in the Gulong sag, Songliao basin, and its geological significance: Evidence from the shale of the Qingshankou Formation[J]. Acta Geologica Sinica,99(2):551-567.

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  • 收稿日期:2023-11-21
  • 最后修改日期:2024-03-20
  • 录用日期:2024-03-20
  • 在线发布日期: 2024-08-01