柴达木盆地东陵湖水化学特征与钾盐分布研究
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本文为国家自然科学联合基金重点项目(编号U21A2018)资助的成果


Study on water chemical characteristics and potash distribution of Dongling Lake in Qaidam basin
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    摘要:

    东陵湖位于柴达木盆地大型钾盐富集基地察尔汗盐湖北部,其浅部石盐层中伴生有光卤石沉积,地勘工作揭示东陵湖浅部边缘地带有寻找低品位固体钾矿的潜力。本文以东陵湖湖表卤水、钻孔晶间卤水、承压卤水、浅层钻孔(0~8 m)盐类沉积物为研究对象,分析研究了东陵湖卤水水化学特征、钻孔沉积物特征及钾盐分布规律,在对比分析察尔汗盐湖钾矿分布特征的基础上,对研究区钾盐成矿作用进行了探讨,主要得出以下结论:① 东陵湖周边凹地钻孔的晶间卤水K+平均含量最高(3. 19 g/L),其次为凹地钻孔承压卤水(1.46 g/L),湖表卤水(0. 74 g/L)和湖区钻孔晶间卤水(0. 79 g/L)K+含量较低;东陵湖卤水样品矿化度(TDS)变化范围较大,介于80. 63~547. 11 g/L之间,不同卤水样品的TDS与K+含量无明显正相关性。② 东陵湖钻孔揭露含盐地层厚4. 2~6. 4 m,岩性以石盐为主,局部含有光卤石沉积,偶见钾石盐;光卤石呈层状和浸染状分布,与石盐呈韵律结构。③ 东陵湖液体钾矿主要分布于湖区西南侧,卤水K+含量为4. 33~6. 29 g/L,KCl品位介于0. 21%~0. 47%之间;固体钾矿主要分布于湖区南侧,沉积物钾含量为2. 05%~4. 86%,KCl含量介于3. 92%~9. 29%之间。④ 东陵湖光卤石沉积区与察尔汗盐湖层状光卤石均沿北缘深大断裂带分布,且后者主要分布于北缘氯化物型水和南缘硫酸镁亚型水混合区域,即达布逊和别勒滩两个洼地北缘,结合Na+、K+、Mg2+、Ca2+//Cl- H2O体系相图和K+- Ca2+相关性分析,认为沿东陵湖南侧深大断裂带补给的Ca- Cl水促进了东陵湖光卤石的沉积。

    Abstract:

    Dongling Lake, located north of the Qarhan Salt Lake, a large potash enrichment zone in the Qaidam basin, exhibits carnallite deposits associated with shallow rock salt layers. Geological exploration indicates the potential for low- grade solid potassium deposits along the lake's shallow periphery. This study investigates the water chemistry, sedimentary features of borehole sediments, and distribution of potassium resources in various brine types (lake surface brines, borehole intercrystalline brines, confined brines) and shallow borehole (0~8 m) salt sediments in Dongling Lake. Additionally, a comparative analysis of potassium deposit distribution in Qarhan Salt Lake is conducted to elucidate the mineralization processes and significance of potassium resources in the study area. Key findings include: ① Intercrystalline brines from the sunken borehole area around Dongling Lake exhibit the highest average K+concentrations (3.19 g/L), followed by confined brines in the sunken borehole (1.46 g/L). Lake surface brines and intercrystalline brines from the lake borehole show relatively lower K+ concentrations of 0.74 g/L and 0.79 g/L, respectively. Salinity (TDS) in Dongling Lake brine samples varies widely, ranging from 80.63 to 547.11 g/L, with no significant positive correlation observed between TDS and K+ concentrations across different brine types. ② Borehole analysis reveals salt- bearing strata with thicknesses ranging from 4.2 to 6.4 m, predominantly composed of stone salt with intermittent carnallite deposits and occasional occurrences of potassium salt. Carnallite exhibits a stratified and rhythmic structure alongside the stone salt. ③ Liquid potassium deposits in Dongling Lake are primarily concentrated in the southwestern region, with K+ concentrations in brines ranging from 4.33 to 6.29 g/L and KCl grades from 0.21% to 0.47%. Solid potassium deposits are predominantly found in the southern part of the lake, exhibiting sedimentary potassium contents ranging from 2.05% to 4.86% and KCl contents between 3.92% and 9.29%. ④ Both the Dongling Lake carnallite sedimentary area and the stratiform carnallite deposits in Qarhan Salt Lake are distributed along the deep fault zone on the northern margin. The latter is mainly found in the mixed zone of chlorine- type water in the north and magnesium sulfate subtype water in the south, specifically within the northern margins of the Dabuxun and Bieletan depressions. Combining Na+, K+, Mg2+, Ca2+//Cl- H2O system phase diagrams with K+- Ca2+ correlation analysis suggests that Ca- Cl water recharge along the deep fault zone south of Dongling Lake facilitated carnallite deposition.

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石海岩,樊启顺,王利文,王明祥,刘万平,李泽仁,李庆宽,陈天源.2024.柴达木盆地东陵湖水化学特征与钾盐分布研究[J].地质学报,98(10):2902-2915.
SHI Haiyan, FAN Qishun, WANG Liwen, WANG Mingxiang, LIU Wanping, LI Zeren, LI Qingkuan, CHEN Tianyuan.2024. Study on water chemical characteristics and potash distribution of Dongling Lake in Qaidam basin[J]. Acta Geologica Sinica,98(10):2902-2915.

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  • 在线发布日期: 2024-10-22