四川盆地东北部黄金口背斜三叠系富K、Li和B卤水成因和演化
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本文为国家自然科学基金项目(编号41402076, 91962219)、中国地质科学院矿产资源研究所基本科研业务费项目(编号KK2210, K1413)和中国地质调查项目(编号DD20230296, DD20221913)联合资助的成果


Genetic evolution of Triassic K- Li- B rich brines in Huangjinkou anticline,northeast Sichuan basin
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    摘要:

    四川盆地东北部地区三叠系嘉陵江组四、五段—雷口坡组一段赋存丰富的卤水资源,卤水中富集K、Li、B等元素,具有潜在的开发利用价值。长期以来,一般认为川东北三叠系中卤水因溶解地层中的钾盐矿物而富集K物质,但这一认识并没有得到确证,此外,对卤水中Li和B的成因和演化鲜有报道。本文以川东北三叠系深层卤水为研究对象,以地球化学和稳定同位素分析为主要方法,运用聚类分析对比采自13口钻井卤水的地球化学数据。与海水相比,区内深层卤水中的K+、Ca2+、Li和B明显富集,而Mg2+和SO2-4则相对亏损。卤水的87Sr/86Sr和δ34S值均与卤水储层的87Sr/86Sr和δ34S值相一致,进一步说明深层卤水为海水原地蒸发浓缩形成。Q型聚类分析表明,北2井和川宣地1井的卤水化学组分相似,川25井、ZK601井、恒成1井、恒成3井的卤水化学组分相近,证明川25井和ZK601卤水中K的富集是由于卤水溶解了地层中的钾盐矿物(杂卤石)。白云岩化导致了卤水中Ca2+明显富集,而Mg2+明显亏损,地层中赋存的硫磺和H2S证明了大量硫酸被还原,使得SO2-4出现明显亏损。还原作用不仅导致卤水和石膏δ34S的升高,而且引起了区域内石膏和卤水的δ34S高于同时期海水的δ34S值。嘉陵江组沉积晚期,三江地区流纹质火山岩浆喷发产生了大量携带含Li和B元素的气体和热液载体,进而被搬运至蒸发盐盆中。火山热液和气体中的Li、B具有相对较低的δ7Li值和δ11B值,在提升卤水中Li和B含量的同时,也降低了卤水δ7Li值和δ11B值,使得其低于正常海水的δ7Li值和δ11B值。

    Abstract:

    The 4th and 5th members of the Jialingjiang Formation and the 1st Member of the Leikoupo Formation in the northeast Sichuan basin host abundant brine resources rich in K, Li, B, and other elements, presenting significant potential for development and utilization. While it has long been assumed that the enrichment of K in Triassic brines in northeast Sichuan is due to the dissolution of potassium salt minerals in the strata, this hypothesis lacks definitive confirmation. In addition, research on the origin and evolution of Li and B in these brines remains limited. In this paper, the deep brine of Triassic in northeast Sichuan Province is taken as the research object. Compared to seawater, these brines exhibit significant enrichment in K+, Ca2+, Li+, and B, while Mg2+and SO2-4are relatively depleted. The 87Sr/86Sr and δ34 S values of the brine are consistent with those of the brine reservoir, suggesting in- situ formation through seawater evaporation and concentration. The Q- type cluster analysis shows that the chemical components of Bei 2 and CXD1 are similar, and the chemical components of C25, ZK601, HC1, and HC3 are similar. It is inferred that the enrichment of K in the brines of C25 and ZK601 is caused by the brine dissolving potassium salt minerals (polyhalite) in the formation. Dolomitization processes lead to the enrichment of Ca2+ and depletion of Mg2+ in the brine. The occurrence of sulfur and H2 S in the formation proves that a large amount of sulfuric acid is reduced, resulting in an obvious loss of SO2-4. The reduction not only elevates the δ34 S values of the brine and gypsum but also causes the δ34 S values of both gypsum and brine in the region to exceed those of contemporaneous seawater. During the late Jialingjiang Formation period, the eruption of rhyolitic magma in the Sanjiang area generated significant quantities of gases and hydrothermal liquids rich in Li and B, which were subsequently transported to evaporite basins. The δ7 Li and δ11 B values of Li and B in volcanic hydrothermal fluids and gases are relatively low. While these fluids increase the Li and B content in the brine, they also decrease the δ7 Li and δ11 B values, making them lower than those of normal seawater.

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牛新生,张永生,苏奎,邢恩袁,左璠璠,桂宝玲,商雯君.2024.四川盆地东北部黄金口背斜三叠系富K、Li和B卤水成因和演化[J].地质学报,98(10):2847-2859.
NIU Xinsheng, ZHANG Yongsheng, SU Kui, XING Enyuan, ZUO Fanfan, GUI Baoling, SHANG Wenjun.2024. Genetic evolution of Triassic K- Li- B rich brines in Huangjinkou anticline, northeast Sichuan basin[J]. Acta Geologica Sinica,98(10):2847-2859.

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  • 收稿日期:2024-06-15
  • 最后修改日期:2024-07-25
  • 录用日期:2024-07-29
  • 在线发布日期: 2024-10-22