湘中涟源南华纪天雄锰矿热水沉积成因地球化学证据
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本文为贵州省科技计划项目(编号:黔科合战略找矿 [2022]ZD003)、黔科合成果[2022]重点003)资助成果


Geochemical evidence forhydrothermal sedimentation genesis of Nanhuan Period Tianxiong manganese deposit in Lianyuan, central Hunan
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  • 1)贵州大学资源与环境工程学院,贵阳,550025;2)贵州省地质矿产勘查开发局一〇三地质大队,贵州铜仁,554300;3)自然资源部基岩区矿产资源勘查工程技术创新中心,贵阳,550081    
  • 1)贵州大学资源与环境工程学院,贵阳,550025;4)贵州大学喀斯特地质资源与环境教育部重点实验室,贵阳,550025    
  • 2)贵州省地质矿产勘查开发局一〇三地质大队,贵州铜仁,554300;3)自然资源部基岩区矿产资源勘查工程技术创新中心,贵阳,550081    
  • 2)贵州省地质矿产勘查开发局一〇三地质大队,贵州铜仁,554300;3)自然资源部基岩区矿产资源勘查工程技术创新中心,贵阳,550081    
  • 2)贵州省地质矿产勘查开发局一〇三地质大队,贵州铜仁,554300;3)自然资源部基岩区矿产资源勘查工程技术创新中心,贵阳,550081    
  • 5)湖南省自然资源调查所,长沙,410007    
  • 2)贵州省地质矿产勘查开发局一〇三地质大队,贵州铜仁,554300;3)自然资源部基岩区矿产资源勘查工程技术创新中心,贵阳,550081    
  • 2)贵州省地质矿产勘查开发局一〇三地质大队,贵州铜仁,554300;3)自然资源部基岩区矿产资源勘查工程技术创新中心,贵阳,550081    
  • 1) College of Resources and Environmental Engineering, Guizhou University, Guiyang, 550025;2) Geological Party 103, Guizhou Bureau of Geology & Mineral Exploration and Development, Tongren, Guizhou 554300    
  • 3)Engineering Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081;4) Key Laboratory of Karst Georesources and Environment, Ministry of Education, Guizhou University, Guiyang, 550025;    
  • 2) Geological Party 103, Guizhou Bureau of Geology & Mineral Exploration and Development, Tongren, Guizhou, 554300;3) Engineering Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081    
  • 2) Geological Party 103, Guizhou Bureau of Geology & Mineral Exploration and Development, Tongren, Guizhou, 554300;3) Engineering Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081    
  • 2) Geological Party 103, Guizhou Bureau of Geology & Mineral Exploration and Development, Tongren, Guizhou, 554300;3) Engineering Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081    
  • 5) Hunan Institute of Natural Resources Survey, Changsha, 410007    
  • 2) Geological Party 103, Guizhou Bureau of Geology & Mineral Exploration and Development, Tongren, Guizhou, 554300;3) Engineering Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081    
  • 2) Geological Party 103, Guizhou Bureau of Geology & Mineral Exploration and Development, Tongren, Guizhou, 554300;3) Engineering Technology Innovation Center of Mineral Resources Explorations in Bedrock Zones, Ministry of Natural Resources, Guiyang, 550081    
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    摘要:

    天雄锰矿是湘中涟源地区具代表性的“大塘坡式”锰矿之一。本文在野外地质调查的基础上结合前人研究成果,对该矿床菱锰矿层及其顶底板围岩详细开展地质地球化学特征分析,结果表明:天雄锰矿矿石构造主要为条纹—条带状,矿石结构主要为碎屑状结构,主要矿石矿物为菱锰矿和钙菱锰矿;菱锰矿层MnO、CaO、MgO含量较顶底板围岩高,TiO2、SiO2、Al2O3含量较顶底板围岩低;含锰岩系微量元素含量平均值与大陆地壳丰度值相比,仅Pb等元素相对富集,Zr、Ta、Cr严重亏损;SiO2/Al2O3值显示锰质来源并非正常陆源,通过计算Al/(Al+Fe+Mn)、(Fe+Mn)/Ti、Fe/Ti比值、Y/Ho值、Nb/Ta值及Fe?Mn?(Cu+Co+Ni)×10、Co/Zn? (Cu+CO+Ni)三角图解,结果显示菱锰矿层具有热水沉积特征;Mn/Fe、Sr/Ba、Th/U、V/(V+Ni)比值表明菱锰矿沉积环境为浅海、次氧化?还原环境;菱锰矿层δEu异常、La/Ce值、ΣREE、ΣLREE/ΣHREE值均反映锰质沉积过程受热水活动影响。湘中天雄锰矿与黔东北松桃锰矿矿集区可能具有相似的深部含锰流体喷溢沉积成矿条件,可参考黔东北“大塘坡式”锰矿找矿研究成果进一步开展工作,争取锰矿找矿新突破。

    Abstract:

    Through geological and elemental geochemical studies, this research identifies hydrothermal sedimentary evidence of the Tianxiong manganese deposit in central Hunan, aiming to provide supplementary insights for metallogenic theory and exploration direction of manganese resources in this region.Methods: Based on petrographic and mineralogical identification, major and trace element analyses of manganese ore beds and their overlying/underlying country rock samples, this study systematically investigates the petrographic characteristics, mineralogical features, and geochemical composition of manganese ores.Results: 1. The predominant manganese-bearing minerals in the Tianxiong Manganese Deposit of central Hunan are rhodochrosite and manganocalcite. 2. Genetic discrimination indicators—including SiO?/Al?O?, Al/(Al+Fe+Mn), Co/Zn-(Cu+Co+Ni), Fe/Ti, Y/Ho diagrams, and the positive Eu anomaly observed in ores—collectively demonstrate that the ore—forming materials of the Tianxiong Deposit were likely derived from submarine hydrothermal systems. 3. Geochemical proxies such as Mn/Fe, V/(V+Ni), and δCe ratios in the manganese-bearing sequences suggest an overall suboxic-reducing depositional environment within a shallow marine facies.Conclusions: The Tianxiong manganese deposit in central Hunan and the Songtao manganese ore cluster in northeastern Guizhou may share similar metallogenic conditions characterized by deep-seated manganese-bearing fluid exhalative sedimentation. Building upon the exploration research framework of the "Datangpo-type" manganese deposits in northeastern Guizhou, further investigations should be prioritized to achieve new breakthroughs in manganese exploration within this region.

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谢兴友,高军波,苏特,冯开友,刘明民,彭桥梁,姚希财,沈红钱.2025.湘中涟源南华纪天雄锰矿热水沉积成因地球化学证据[J].地质论评,71(3):2025030010,[DOI].
XIE Xingyou, GAO Junbo, SU Te, FENG Kaiyou, LIU Mingmin, PENG Qiaoliang, YAO Xicai, SHEN Hongqian.2025. Geochemical evidence forhydrothermal sedimentation genesis of Nanhuan Period Tianxiong manganese deposit in Lianyuan, central Hunan[J]. Geological Review,71(3):2025030010.

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  • 收稿日期:2024-10-29
  • 最后修改日期:2025-04-19
  • 在线发布日期: 2024-05-19
  • 出版日期: 2025-05-15